PROSITE documentation PDOC00132

Asparaginase / glutaminase active sites signatures

Description:

Asparaginase (EC 3.5.1.1), glutaminase (EC 3.5.1.2) and glutaminase-asparaginase (EC 3.5.1.38) are aminohydrolases that catalyze the hydrolysis of asparagine (or glutamine) to aspartate (or glutamate) and ammonia [1].

Two conserved threonine residues have been shown [2,3] to play a catalytic role. One of them is located in the N-terminal extremity while the second is located at the end of the first third of the sequence. We used both conserved regions as signature patterns.

Note:

Plant asparaginases and mammalian glutaminases do not belong to this family and are thus not detected by the above pattern.

Expert(s) to contact by email:

Gribskov M.

Last update:

April 2006 / Pattern revised.

Technical section:

PROSITE methods (with tools and information) covered by this documentation:

ASN_GLN_ASE_1, PS00144Asparaginase / glutaminase active site signature 1  (PATTERN)
Consensus pattern: [LIVM]-x-{L}-T-G(2)-T-[IV]-[AGS]
The second T is an active site residue
Sequences known to belong to this class detected by the pattern: ALL
Other sequence(s) detected in Swiss-Prot: 10.
• Retrieve an alignment of Swiss-Prot true positive hits:
  Clustal format, color, condensed view  / Clustal format, color  / Clustal format, plain text  / Fasta format
Retrieve the sequence logo from the alignment
Taxonomic tree view of all Swiss-Prot/TrEMBL entries matching PS00144
Retrieve a list of all Swiss-Prot/TrEMBL entries matching PS00144
Scan Swiss-Prot/TrEMBL entries against PS00144
view ligand binding statistics
Matching PDB structures: 1AGX 1DJO 1DJP 1HFJ ... [ALL]
ASN_GLN_ASE_2, PS00917Asparaginase / glutaminase active site signature 2  (PATTERN)
Consensus pattern: [GA]-x-[LIVM]-x(2)-H-G-T-D-T-[LIVM]
The first T is an active site residue
Sequences known to belong to this class detected by the pattern: ALL
Other sequence(s) detected in Swiss-Prot: NONE.
• Retrieve an alignment of Swiss-Prot true positive hits:
  Clustal format, color, condensed view  / Clustal format, color  / Clustal format, plain text  / Fasta format
Retrieve the sequence logo from the alignment
Taxonomic tree view of all Swiss-Prot/TrEMBL entries matching PS00917
Retrieve a list of all Swiss-Prot/TrEMBL entries matching PS00917
Scan Swiss-Prot/TrEMBL entries against PS00917
view ligand binding statistics
Matching PDB structures: 1AGX 1DJO 1DJP 1HFJ ... [ALL]

References:

1 AuthorsTanaka S., Robinson E.A., Appella E., Miller M., Ammon H.L., Roberts J., Weber I.T., Wlodawer A.
TitleStructures of amidohydrolases. Amino acid sequence of a glutaminase-asparaginase from Acinetobacter glutaminasificans and preliminary crystallographic data for an asparaginase from Erwinia chrysanthemi.
SourceJ. Biol. Chem. 263:8583-8591(1988).
PubMed ID3379033
2 AuthorsHarms E., Wehner A., Aung H.P., Rohm K.H.
TitleA catalytic role for threonine-12 of E. coli asparaginase II as established by site-directed mutagenesis.
SourceFEBS Lett. 285:55-58(1991).
PubMed ID1906013
3 AuthorsMiller M.M., Rao J.K.M., Wlodawer A., Gribskov M.R.
TitleA left-handed crossover involved in amidohydrolase catalysis. Crystal structure of Erwinia chrysanthemi L-asparaginase with bound L-aspartate.
SourceFEBS Lett. 328:275-279(1993).
PubMed ID8348975

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